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This research aim is to obtain practical design of purifying bioethanol using distillation device with  condenser of household plastic waste to increase student creativity on petroleum materials. Bioethanol that used made of nira aren fermentation in Kapuntori Subdistrict, Buton Regency. This research method is ADDIE development (Analysis, Design, Development, Implementation, and Evaluation). However, this research method only did until the implementation step practical design, where student can create a set of distillation apparatus with condenser from household plastic waste by looking at the description of the distillation device and practical design which has optimization and valid. In necessity analysis, the researcher analyzed literature study and field study. After this, the next step is design step, in this step the researcher plan a bioethanol practical work design and a simple set of distillation devices with condensers from household plastic waste then consul about it with an expert lecturer of  bioethanol purifying. After the design step, the next is development step, the researcher did optimization process for 3 times. The optimization process aims to obtain optimal results and validity of the practice design to be used as a reference when the process of implimentasi in school. After optimization process then implementation in class XI MIA 3 SMAN 1 Kapuntori petroleum material and obtain 3 distillation device with condenser from different plastic household waste and can be used for bioethanol purification process proved with the result obtained.

Practical Design, Purification Bioethanol, Simple Distillation, Creativity